Cumene is made by alkylation of benzene with propylene over a zeolitic catalyst. To maximize selectivity to desired products, several beds of catalyst are used inside the same reactor. A mixture of feed and recycle benzene enters the top of the reactor, and the feed propylene is split so that a portion of the propylene is fed to each catalyst bed. A large excess of benzene is used to minimize propylene oligomerization and ensure complete reaction of propylene. The reactor product is cooled and sent to a stabilizer column that removes any light hydrocarbons. The bottoms from this column are sent to a benzene column that recovers benzene overhead for recycle to the alkylation and transalkylation reactors. The bottoms from the benzene column are distilled to give cumene product and a heavy stream. The heavy stream is further distilled in a heavies column to give a mixture of dipropyl- and tripropyl-benzene overhead and a heavy waste stream as bottoms. The distillate from the heavies column is sent to a transalkylation reactor and reacted with excess benzene. The product from the transalkylation reactor is returned to the benzene column. Sketch a block flow diagram of the process.

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